The Stereochemistry of Reduction of 3-Phenyl-1-tetralone and 3-Methyl-1-tetralone
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چکیده
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Conversion of 1- and 2-Tetralone Over HY Zeolite
Conversion of 1and 2-tetralone was investigated over acid HY zeolite under various reaction conditions in the vapor phase. Reactions were conducted in a fixed-bed reactor at 300, 400 and 500 C in hydrogen atmospheric pressure. It was found that 1and 2-tetralone are thermally unstable and thermal reaction has a contribution, particularly at high temperatures. The reactivity of 2-tetralone was si...
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The syntheses of the title compounds are described. 1- [[2- Amino -1 - (hydroxymethyl) ethoxy] methyl] uracil exhibitslittleactivity against herpesviruses (HSV) in vivo
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A new 2-[(4-substituted-phenyl-3-chloroazetidin-2-one)-5-(2'-methylamino 4-phenyl-1', 3'-thiazolyl-]-1, 3, 4-thiadiazoles, 5(a-n) were synthesized from 2-substituted-benzylideneamino-5-[2'-methylamino-4'-phenyl-1',3'-thiazolyl]-1,3, 4-thiadiazole, 4(a-n) using 2-amino-4phenyl-1, 3-thiazole as a starting material. The synthesised compounds have been screened in vitro for their antimicrobial acti...
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The necessary conditions to transform hydroxyamide (1) and 2-oxazolines (2, 3) into 3- or 4-methyl benzo[f] isoquinolines (4, 5) has been established. The mechanism of these reactions has been proposed claiming the existence of the protonated 2-oxazoline (6) and the styrylamides (7) as intermediates.
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In the title compound, C(23)H(19)N(3)O(2), the dihedral angles formed by the pyrazolone ring with the three benzene rings are 30.91 (6), 60.96 (4) and 57.01 (4)°. The ligand is in the enamine-keto form and its structure is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, O-H⋯N hydrogen bonds link mol-ecules into chains parallel to [01-1].
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1966
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.87.9_995